Important Questions Class 12 Chemistry Chapter 13 - Amines 3 Marks Questions


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Important Questions Class 12 Chemistry Chapter 13 – Amines

CBSE Class 12 Chemistry Important Questions Chapter 13 – Amines


3 Marks Questions

1.

Ans.

2.A compound (X) having formula C3H7 NO reacts with Br2 in the presence of NaOH to give another compound (Y). Compound (Y) reacts with HNO2 to form ethanol and gas . Identify (X) and (Y) . Write the reaction involved.
Ans.

Since Y gives ethanol and gas with, therefore it is.
Ethan amine (Y) is formed on reacting (X) with and NaOH;
Therefore X is.
Therefore
X=
Y = 
The reactions are –

 
3.An organic compound A on boiling with alkali gives and sodium salt of an acid B. The compound A on reduction gives which on treatment with nitrous acid gives an alcohol. Identify A to D
Ans.

Since the compound (A) gives sodium salt and ammonia, (A) is cyanide. The compound (C) is a primary amine as it reacts with and forms an alcohol (D) Therefore
A=,B= 
C=,D= 
Equations are-

 
4.

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5.

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6.

Ans.

 
7.

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8.

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9.

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10.

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11.How will you convert?
(i) Benzene into aniline
(ii) Benzene into N, N-dimethylaniline
(iii) into hexan-1, 6-diamine?
Ans.(i)
14361952985728.png
(ii)
14361952996428.png
(iii)
1436195301732.png
12. Write reactions of the final alkylation product of aniline with excess of methyl iodide in the presence of sodium carbonate solution.
Ans.Aniline reacts with methyl iodide to produce N, N-dimethylaniline.
14361953247005.png
With excess methyl iodide, in the presence of solution, N, N-dimethylaniline produces N, N, N-trimethylanilinium carbonate.
14361953257758.png
13.Convert
(i) 3-Methylaniline into 3-nitrotoluene.
(ii) Aniline into 1, 3, 5-tribromobenzene.
Ans.(i)
14361953424355.png
(ii)
14361953434529.png