Determination Of Melting Point Of An Organic Compound

Chemical compounds which contain carbon is known as an organic compound. Study of manufacturing and synthesis of chemical compounds is known as organic chemistry. The temperature at which the chemical compound changes its state from solid to liquid is said to be the melting point of the compound. Let us learn to determine the melting point of organic compounds like naphthalene and benzoic acid.

Aim:

To determine the melting point of organic compounds like Naphthalene and benzoic acid.

Materials Required:

Naphthalene, benzoic acid, the aluminium block, stand with clamp, capillary tube, tripod, thermometer, and kerosene burner

Experimental setup:

Procedure to determine the melting point of Naphthalene:

1. Take a capillary tube and close its one end by heating the end in the flame for 2-3 minutes while continuously rotating it.
2. Take naphthalene on a tile and crush it into a fine powder.
3. As shown in the figure below, firmly hold the closed end of the capillary tube between your finger and thumb.
4. Dip the open end of the capillary tube in the finely powdered naphthalene.
5. Gently tap the capillary tube on the table to fill the compound in the capillary tube to about a length of 1–2 cm.

Figure (b)

1. Place the capillary tube in the groove of the aluminium block.
2. Double check that the capillary tube holding the naphthalene is in the middle of the groove.
3. Place the Aluminium block on a tripod stand above the kerosene burner and start heating the block with the burner.
4. Keep continuous watch of the temperature and note the temperature as soon as the substance starts to melt.
5. Make note of the temperature (t1) as soon as the compound begins to melt.
6. Make note of the temperature (t2) as soon as the compound is melted completely.
7. The average of the two readings gives the correct melting point of the substance.

Procedure to determine the melting point of Benzoic Acid:

1. Take Benzoic acid on a tile and crush it into a fine powder.
2. Take a capillary tube and by heating one end close the end of the tube.
3. Hold the closed end of the capillary tube between your finger and thumb as shown in figure (a) above.
4. Dip the open end of the capillary tube in the finely powdered Benzoic acid.
5. Fill the compound in the capillary tube to about a length of 1–2 cm by gently tapping the capillary.
6. Attach the thermometer to a capillary tube using a thread as shown in the figure (b) above.
7. Place the capillary tube in the groove of the aluminium block.
8. Check if the capillary tube holding the benzoic acid is exactly in the middle of the groove.
9. Place the Aluminium block on a tripod stand above the kerosene burner and start heating the block with the burner.
10. Keep continuous watch of the temperature and note the temperature as soon as the substance starts to melt.
11. Note the temperature (t1) as the substance begins to melt.
12. Make a note of the temperature (t2) when the substance has completely melted.
13. The average temperature of the substance is determined.

Precautions to be taken during the experiment:

• Make sure the sample of Naphthalene and Benzoic acid are dry and powdered.
• Keep the capillary tube and the thermometer at a similar level.
• Tightly pack the powder into the capillary tube without any air gaps.

Observation

Temperature observation of Naphthalene

Temperature observation of Benzoic acid